Jibakurai

First appeared as a Demi-Hollow that was chained at the hospital. Don Kanonji accidentally transformed him by removing his Chain of Fate. His Hollow form resembles a frog. Ichigo Kurosaki managed to kill the Hollow and clean up Don Kanonji's mistake. His main attack is a spitting slime that bonds and solidifies whatever it attaches to. He uses this to bond Ichigo's sword to both his own hands and to the guard rail of the hospital roof.